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2,2′-Bisdinitromethyl-5,5′-bistetrazole: A High-Performance, Multi-Nitro Energetic Material with Excellent Oxygen Balance

Yiling Yang, Wenjin Zhang, Siping Pang, He Huang, Chenghui Sun

2024The Journal of Organic Chemistry11 citationsDOI

Abstract

Bistetrazoles are highly sought after for developing innovative high-energy density materials. The 1,1'-substituted bistetrazoles, exemplified by TKX-50, have outstanding performance. However, the research of high-perfomance 2,2'-substituted bistetrazoles remains limited. In this work, dinitromethyl groups were introduced into bistetrazole structures as 2,2'-substituted bistetrazoles (BDBTZ), which was extensively characterized through NMR, thermal analysis, and single crystal X-ray diffraction, exhibiting excellent oxygen balance, moderate sensitivity, acceptable thermal stability, high crystal density, and excellent detonation performance.

Topics & Concepts

Oxygen balanceThermal stabilityNitroDetonationEnergetic materialMaterials scienceOxygenCrystal structureThermalChemical engineeringSingle crystalChemistryCrystallographyExplosive materialOrganic chemistryThermodynamicsPhysicsAlkylEngineeringEnergetic Materials and CombustionThermal and Kinetic AnalysisChemical Reactions and Mechanisms