Constructing spin crossover-fluorescence bifunctional iron(<scp>ii</scp>) complexes based on tetraphenyl ethylene-decorated AIEgens
Yi Cheng, Shihui Zhang, Liang Zhao, Nian‐Tao Yao, Guo-Hui Zhao, Yin‐Shan Meng, Tao Liu
Abstract
of 375, 260, and 248 K, respectively. Fluorescence measurements confirmed the existence of the AIE property for both the tpe-bpp ligand and Fe(II) complexes. A monotonic decrease of the photoluminescence (PL) intensity upon increasing the temperature was behavior observed for all three complexes.
Topics & Concepts
BifunctionalSpin crossoverLigand (biochemistry)ChemistryFluorescenceCrystallographyCounterionPhotoluminescencePyridineAggregation-induced emissionTetraphenylethylenePhotochemistryIonMaterials scienceMedicinal chemistryOrganic chemistryCatalysisQuantum mechanicsBiochemistryReceptorPhysicsOptoelectronicsMagnetism in coordination complexesLuminescence and Fluorescent MaterialsLanthanide and Transition Metal Complexes