ScVO<sub>4</sub>:Bi<sup>3+</sup> thermographic phosphor particles for fluid temperature imaging with sub-°C precision
Christopher Abram, Irin Wilson Panjikkaran, Simon N. Ogugua, Benoît Fond
Abstract
We synthesized and characterized <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">S</mml:mi> <mml:mi mathvariant="normal">c</mml:mi> <mml:mi mathvariant="normal">V</mml:mi> </mml:mrow> </mml:mrow> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:msub> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">O</mml:mi> </mml:mrow> </mml:mrow> <mml:mn>4</mml:mn> </mml:msub> </mml:mrow> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mo>:</mml:mo> </mml:mrow> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">B</mml:mi> </mml:mrow> </mml:mrow> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:msup> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">i</mml:mi> </mml:mrow> </mml:mrow> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mn>3</mml:mn> <mml:mo>+</mml:mo> </mml:mrow> </mml:msup> </mml:mrow> </mml:math> thermographic phosphor particles and demonstrated their use as a tracer for temperature imaging in a near-ambient temperature liquid flow using a single laser/camera luminescence lifetime dual-frame ratio-based method. Owing to a high temperature sensitivity of up to 6%/°C, the single-shot single-pixel temperature precision at a 400 µm spatial resolution is better than <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mo>±</mml:mo> <mml:mn>0</mml:mn> </mml:mrow> <mml:mo>.</mml:mo> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:msup> <mml:mn>4</mml:mn> <mml:mo>∘</mml:mo> </mml:msup> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mi mathvariant="normal">C</mml:mi> </mml:mrow> </mml:mrow> </mml:mrow> </mml:math> ( <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mn>1</mml:mn> </mml:mrow> </mml:mrow> <mml:mi>σ</mml:mi> </mml:math> ) across the 20 to 60°C range, representing a factor <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML" display="inline"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mo>></mml:mo> </mml:mrow> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mrow class="MJX-TeXAtom-ORD"> <mml:mn>5</mml:mn> </mml:mrow> </mml:mrow> </mml:math> improvement compared to previous works using thermographic phosphors. The measurement duration is on the order of the luminescence lifetime (2 µs), which is applicable in both gas and liquid flows. This is a general temperature imaging method for sensitive measurements in dynamic fluid mechanics and thermal science applications.