Pyridylpyrrolido ligand in Ge(<scp>ii</scp>) and Sn(<scp>ii</scp>) chemistry: synthesis, reactivity and catalytic application
Sanjukta Pahar, Vishal Sharma, Srinu Tothadi, Sakya S. Sen
Abstract
SiF by utilizing the fluoride affinity of the silicon atom. As there is scarcity of Sn(II) compounds as single-site catalysts, we investigated 5 as a catalyst towards the hydroboration of aldehydes, ketones, alkenes and alkynes. All the compounds have been characterized by single-crystal X-ray diffraction and by state of the art spectroscopic studies.
Topics & Concepts
TransmetalationChemistryTrimethylsilylHydroborationLigand (biochemistry)Reactivity (psychology)MoietyCatalysisPyridineMedicinal chemistrySilyleneSilylationTrisSingle crystalStereochemistryPolymer chemistryCrystallographyOrganic chemistrySiliconPathologyReceptorBiochemistryAlternative medicineMedicineSynthesis and characterization of novel inorganic/organometallic compoundsCoordination Chemistry and OrganometallicsOrganoboron and organosilicon chemistry