Selective nickel-catalyzed disulfuration of alkyl halides with di/trithiosulfonates
Lulu Liu, Jiaqi Hou, Yingying Ma, Hongwei Wang, Yu Zhong, Fangcan Liang, Luyao Wang, Qingling Wang, Jiquan Liu, Wenhua Xu, Dianhu Zhu
Abstract
Selective reductive disulfuration of alkyl halides with di/trithiosulfonate reagents was developed through ligand regulation, with key features of broad substrate scope, good tolerance and excellent selectivity to disulfides over trisulfides.
Topics & Concepts
ChemistryHalideAlkylReagentNickelCatalysisLigand (biochemistry)SelectivitySubstrate (aquarium)Combinatorial chemistryScope (computer science)Organic chemistryBiochemistryReceptorOceanographyComputer scienceProgramming languageGeologySulfur-Based Synthesis TechniquesChemical Synthesis and ReactionsOrganoselenium and organotellurium chemistry