Effects of support porosity of Co-Mo/MgO catalyst on methane catalytic decomposition for carbon and hydrogen production
Dong Hyun Ko, Seok Chang Kang, Chul Wee Lee, Ji Sun Im
Abstract
To investigate the effects of porous properties of supports on the methane decomposition of Co-Mo/MgO catalysts, supports having different porous properties were prepared by varying the synthesis temperature of MgO. Co-Mo/MgO catalysts were prepared using the impregnation method. The CM/4MgO catalyst using 4MgO support, which had the largest specific surface area of 170 m2/g, showed highest methane conversion of 85.7 % with 60.12 % of MWCNT production. The produced MWCNT on CM/4MgO had highest crystallinity and electrical conductivity with average diameter of 20.5 ± 7.8 nm. Overall, the improved pore structure of MgO prepared by the oxidation process enhanced the dispersibility of the Co active metal, thereby improving methane conversion and MWCNT production.