Copper Tetracyanoquinodimethane (CuTCNQ): A Metal–Organic Semiconductor for Room-Temperature Visible to Long-Wave Infrared Photodetection
Sivacarendran Balendhran, Zakir Hussain, Vivek Raj Shrestha, Jasper J. Cadusch, Ming Ye, Nima Sefidmooye Azar, Hyung‐Jin Kim, Rajesh Ramanathan, James Bullock, Ali Javey, Vipul Bansal, Kenneth B. Crozier
Abstract
Mid-wave and long-wave infrared (MWIR and LWIR) detection play vital roles in applications that include health care, remote sensing, and thermal imaging. However, detectors in this spectral range often require complex fabrication processes and/or cryogenic cooling and are typically expensive, which motivates the development of simple alternatives. Here, we demonstrate broadband (0.43-10 μm) room-temperature photodetection based on copper tetracyanoquinodimethane (CuTCNQ), a metal-organic semiconductor, synthesized via a facile wet-chemical reaction. The CuTCNQ crystals are simply drop-cast onto interdigitated electrode chips to realize photoconductors. The photoresponse is governed by a combination of interband (0.43-3.35 μm) and midgap (3.35-10 μm) transitions. The devices show response times (∼365 μs) that would be sufficient for many infrared applications (e.g., video rate imaging), with a frequency cutoff point of 1 kHz.