Tuning chain topologies and magnetic anisotropy in one-dimensional cobalt(<scp>ii</scp>) coordination polymers <i>via</i> distinct dicarboxylates
Zhengfang Tian, Shruti Moorthy, Xiang Huan, Peng Peng, Maolin You, Qian Zhang, Shun-Yi Yang, Yang-Lu Zhang, Dongqing Wu, Saurabh Kumar Singh, Dong Shao
Abstract
Two 1D Co( ii ) coordination polymers constructed by mixed terpyridine–dicarboxylate bridges were structurally and magnetically characterized to show slow magnetic relaxation, distinct chain topologies, and magnetic anisotropy tuned by dicarboxylates.
Topics & Concepts
Chain (unit)PolymerMagnetic anisotropyCobaltAnisotropyNetwork topologySingle chainMaterials scienceMagnetic relaxationCoordination polymerTopology (electrical circuits)CrystallographyPolymer chemistryChemistryMagnetic fieldPhysicsComputer scienceMagnetizationCombinatoricsComposite materialComputer networkBiologyAstronomyMetallurgyQuantum mechanicsAntibodyImmunologyMathematicsMetal-Organic Frameworks: Synthesis and ApplicationsMagnetism in coordination complexesLanthanide and Transition Metal Complexes