Green mechanochemical synthesis of imine-linked covalent organic frameworks for high iodine capture
Normanda Brown, Ziad Alsudairy, Ranjan Kumar Behera, Fazli Akram, Kuangcai Chen, Kayla Smith-Petty, Bria Motley, Spirit Williams, Wenyu Huang, Conrad W. Ingram, Xinle Li
Abstract
Delineated here is the first mechanochemical synthesis of covalent organic frameworks (COF) adsorbents that exhibited exceptional iodine adsorption capacities of 6.4–7.1 g g −1 , surpassing those of most existing COFs.
Topics & Concepts
Covalent bondImineIodineCovalent organic frameworkAdsorptionChemistryOrganic synthesisCombinatorial chemistryOrganic chemistryDynamic covalent chemistryMechanochemistryChemical engineeringMoleculeCatalysisSupramolecular chemistryEngineeringCovalent Organic Framework ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsLuminescence and Fluorescent Materials