A slowly magnetic relaxing Sm<sup>III</sup> monomer with a <i>D</i><sub>5h</sub> equatorial compressed ligand field
Yong-Ze Pan, Qiu-Yan Hua, Li-Shan Lin, Yibo Qiu, Jun‐Liang Liu, Ai‐Ju Zhou, Wei‐Quan Lin, Ji‐Dong Leng
Abstract
A <italic>D</italic><sub>5h</sub> equatorial compressed ligand field of the central Ln<sup>III</sup> ion is achieved. The samarium complex is the first Sm<sup>III</sup> mono-nuclear complex with slow magnetic relaxation. The Dy<sup>III</sup> analogue, in contrast, relaxes much faster
Topics & Concepts
SamariumLigand (biochemistry)IonLigand field theoryRelaxation (psychology)CrystallographyField (mathematics)Magnetic fieldPhysicsChemistryAtomic physicsNuclear magnetic resonanceNuclear physicsQuantum mechanicsMathematicsPsychologyPure mathematicsSocial psychologyReceptorBiochemistryMagnetism in coordination complexesLanthanide and Transition Metal ComplexesElectron Spin Resonance Studies