Real-time microscopy of the relaxation of a glass
Marta Ruiz-Ruiz, Ana Vila-Costa, Tapas Bar, Cristian Rodríguez-Tinoco, Marta González-Silveira, J.A. Plaza, Jorge Alcalá, Jordi Fraxedas, J. Rodríguez‐Viejo
Abstract
Abstract The understanding of the dynamics of a glass above its devitrification temperature remains incomplete. Here, we build a spatio-temporal map of the relaxation dynamics of a highly stable glass into its supercooled liquid using real-time atomic force microscopy imaging. This methodology enables direct visualization of the progression of the liquid phase and clarifies and quantifies the presence of localized fast mobility regions separated by giant length scales. Our data establish a clear correlation between dynamic length and time scales in glasses. This approach may also be applicable to unveil the microscopic structure and dynamics of other glass-forming systems with much shorter length and time scales, including liquid-cooled glasses.