A mixed-valence Cu<sup>I</sup>/Cu<sup>II</sup> metal–organic framework for CO<sub>2</sub> conversion
Yumei Wang, Kai‐Ming Mo, Dong Luo, Mei-Xia Tao, Chen Xu, Guo‐Hong Ning, Dan Li
Abstract
A Cu I /Cu II mixed-valence metal–organic framework with a rarely reported (3,4,4)-c network topology has been prepared. It can effectively catalyze the cyclization reaction of epoxides or propargyl amines with carbon dioxide.
Topics & Concepts
Valence (chemistry)MetalCopperChemistryPropargylInorganic chemistryCarbon dioxideCatalysisOrganic chemistryMetal-Organic Frameworks: Synthesis and ApplicationsCarbon dioxide utilization in catalysisCO2 Reduction Techniques and Catalysts