Stereoselective Diels–Alder Reactions of <i>gem</i> -Diborylalkenes: Toward the Synthesis of <i>gem-</i> Diboron-Based Polymers
Nadim Eghbarieh, Nicole Hanania, Alon Zamir, Molhm Nassir, Tamar Stein, Ahmad Masarwa
Abstract
diboron-based polymers. Additionally, these polymers have been successfully submitted to postpolymerization modification reactions. Given its simplicity and versatility, we believe that this novel DA and ROMP approach holds great promise for organoboron synthesis as well as organoboron-based polymers and that it will result in more novel transformations in both academic and industrial research.
Topics & Concepts
ChemistryStereoselectivityRegioselectivityROMPReagentCombinatorial chemistryMetathesisOrganic synthesisPolymerizationOrganic chemistryPolymerCatalysisOrganoboron and organosilicon chemistrySynthetic Organic Chemistry MethodsCatalytic Cross-Coupling Reactions