Photo-CIDNP in Solid State
Jörg Matysik, Yonghong Ding, Yunmi Kim, Patrick Kurle, Alexandra V. Yurkovskaya, Konstantin L. Ivanov, A. Alia
Abstract
Photo-CIDNP (photo-chemically induced dynamic nuclear polarization) refers to nuclear polarization created by the spin-chemical evolution of spin-correlated radical pairs (SCRPs). This phenomenon occurs in gases, liquids and solids. Based on the solid-state photo-CIDNP effect observed under magic-angle spinning (MAS), photo-CIDNP MAS NMR has been developed as analytical method. Here we report the origin, the theory and the state of the art of this method.
Topics & Concepts
CIDNPSolid-state physicsPolarization (electrochemistry)Solid-stateMagic angle spinningChemical physicsMaterials scienceSolid-state nuclear magnetic resonanceSpinningChemistryPhysicsNuclear magnetic resonanceCondensed matter physicsNuclear magnetic resonance spectroscopyPhysical chemistryPolymer chemistryAdvanced Chemical Physics StudiesSpectroscopy and Quantum Chemical StudiesAdvanced NMR Techniques and Applications