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Low Energy Blue Pulsed Light‐Activated Injectable Materials for Restoring Thinning Corneas

Aidan J. MacAdam, Marcelo Muñoz, Jinane El Hage, Kevin Hu, Alex Ross, Astha Chandra, Jodi D. Edwards, Zian Shahid, Sophia Mourcos, Maxime Comtois‐Bona, Alejandro Juárez, Marc Groleau, Delali Shana Dégué, Mohamed Djallali, Marilyse Piché, Mathieu Thériault, Michel Grenier, May Griffith, Isabelle Brunette, Emilio I. Alarcón

2023Advanced Functional Materials12 citationsDOIOpen Access PDF

Abstract

Abstract Many alternatives to human donor corneas are being developed to meet the global shortage of donated tissues. However, corneal transplantation remains the gold standard for diseases resulting in thinning corneas. In this study, transparent low energy photoactivated extracellular matrix‐mimicking materials are developed for intrastromal injection to restore stromal thickness. The injectable biomaterials are comprised of short peptides and glycosaminoglycans (chondroitin, hyaluronic acid) that assemble into a hydrogel when pulsed with low‐energy blue light. The dosage of pulsed‐blue light needed for material activation is minimal at 8.5 mW cm −2 , thus circumventing any blue light cytotoxicity. Intrastromal injection of these light‐activated biomaterials in rat corneas shows that two iterations of the formulations remain stable in situ without stimulating significant inflammation or neovascularization. The use of low light intensities and the ability of the developed materials to stably rebuild and change the curvature of the cornea tissue make these formulations attractive for clinical translation.

Topics & Concepts

Materials scienceCorneaBiomedical engineeringStromal cellExtracellular matrixTransplantationSelf-healing hydrogelsCorneal transplantationHyaluronic acidBlue lightEconomic shortageOptoelectronicsSurgeryOphthalmologyMedicineChemistryCancer researchAnatomyLinguisticsGovernment (linguistics)Polymer chemistryBiochemistryPhilosophyCorneal surgery and disordersCorneal Surgery and TreatmentsOcular Surface and Contact Lens
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