Compact accumulation of superatomic silver nanoclusters with an octahedral Ag<sub>6</sub> core ligated by trithiane
Xun Cheng, Rui-Ru Zhong, Shang‐Fu Yuan, Zong‐Jie Guan, Kuan‐Guan Liu
Abstract
] (Ag6), have been described here, which are both close-packed in the crystal lattice with the ligation of trithiane. Their aggregation-state-dependent absorption and fluorescence properties could be ascribed to the enhanced intercluster charge-transfer in the crystalline state.
Topics & Concepts
NanoclustersOctahedronMaterials scienceCore (optical fiber)CrystallographyNanotechnologyChemistryComposite materialCrystal structureNanocluster Synthesis and ApplicationsGold and Silver Nanoparticles Synthesis and ApplicationsRandom Matrices and Applications