Green synthesis of imine-based covalent organic frameworks in water
Jesús Á. Martín‐Illán, David Rodríguez‐San‐Miguel, Carlos Franco, Inhar Imaz, Daniel Maspoch, Josep Puigmartí‐Luis, Félix Zamora
Abstract
Dynamic covalent bonds have been advantageously used to direct the synthesis of crystalline porous covalent organic frameworks (COFs). Unlike the standard synthetic protocols that involve harsh conditions, this work provides a high-yield "one-pot" green synthesis of imine-based COFs in water. Additionally, this aqueous synthesis can be performed under microwave conditions, considerably reducing the reaction time.
Topics & Concepts
ImineCovalent bondAqueous solutionYield (engineering)Covalent organic frameworkChemistryCombinatorial chemistryMaterials scienceOrganic chemistryCatalysisMetallurgyCovalent Organic Framework ApplicationsMetal-Organic Frameworks: Synthesis and ApplicationsAdvanced Photocatalysis Techniques