Ru(dppbsa)-catalyzed hydrodeoxygenation and reductive etherification of ketones and aldehydes
Rui Sun, Hongyu Guo, Shuangshuang Ma, Yaofeng Wang, Zhengkun Yu, Bao‐Hua Xu
Abstract
Methods for the Ru(dppbsa)-catalyzed hydrodeoxygenation and reductive etherification of ketones and aldehydes were developed. Mechanistic studies suggest two paths with respective rate-limiting step to distinct carbonyl substrates.
Topics & Concepts
HydrodeoxygenationChemistryCatalysisLimitingOrganic chemistryKetoneMedicinal chemistrySelectivityEngineeringMechanical engineeringAsymmetric Hydrogenation and CatalysisCatalysis for Biomass ConversionNanomaterials for catalytic reactions