Pd( <scp>ii</scp> )-catalyzed B(9)-alkynylation of <i>o</i> / <i>m</i> -carboranes
Haotian Zhang, Yan Gao, Yan‐Na Ma, Xuenian Chen
Abstract
Pd( ii )-catalyzed selective B(9)-alkynylation of o -carboranes and m -carboranes with i Pr 3 SiCCBr as the alkynylated reagent was developed. Further transformation of the products provided diverse carborane derivatives.
Topics & Concepts
ChemistryAlkynylationCatalysisMedicinal chemistryCombinatorial chemistryOrganic chemistryBoron Compounds in ChemistryRadiopharmaceutical Chemistry and ApplicationsMedical Imaging Techniques and Applications