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Covalent Bonding of MXene/Reduced Graphene Oxide Composites for Efficient Electromagnetic Wave Absorption

Fengxia Yang, Ying Huang, Xiaopeng Han, Shuai Zhang, Meng Yu, Junping Zhang, Xu Sun

2023ACS Applied Nano Materials32 citationsDOI

Abstract

Due to their high conductivity and unique surface chemical characteristics, MXene and reduced graphene oxide (rGO) have received a great deal of attention in the field of electromagnetic wave absorption (EMA). This study describes the covalent modification of rGO with amino-functionalized MXene to create an electromagnetic absorbent material called MXene-rGO composite. After amidation, an amide bond successfully assembles MXene and rGO. The absorber performs admirably when the mass ratio of MXene to rGO is 1:2 (sample MG-3). With a thickness of 2.7 mm, the best reflection loss (R L ) is −47.98 dB at 6.4 GHz. Additionally, the best effective absorption bandwidth (EAB) (R L < −10 dB) is 4.08 GHz (11.84–15.92 GHz) with a 1.4 mm matching thickness. The performance of the EMA can be obtained by adjusting the dielectric parameters and the migration rate of the electrons using the covalent bond as a stable carrier channel. The high dielectric loss, superior impedance matching, and strong attenuation ability contribute to the great absorption performance.

Topics & Concepts

GrapheneMaterials scienceCovalent bondReflection lossOxideDielectricComposite materialAbsorption (acoustics)Electromagnetic radiationMicrowaveComposite numberImpedance matchingDielectric lossElectrical impedanceOptoelectronicsNanotechnologyOpticsChemistryOrganic chemistryTelecommunicationsComputer scienceEngineeringPhysicsMetallurgyElectrical engineeringElectromagnetic wave absorption materialsAdvanced Antenna and Metasurface TechnologiesAntenna Design and Analysis
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