K Intercalation-Assisted Co-Doped MoS<sub>2</sub> Nanoflowers for an Efficient Hydrogen Evolution Reaction
Minkai Qin, Menghui Qi, Ruxue Fan, Jiadong Chen, Xiaoyun Shi, Binbin Lin, Lingling Xi, Yong Wang
Abstract
High Resolution Image Download MS PowerPoint Slide 2D transition metal disulfides have emerged as promising Pt-alternative electrocatalysts for hydrogen generation. However, the sluggish water dissociation kinetics and limited active sites hinder their performance in alkaline media. Herein, we propose a two-step hydrothermal method to synthesize K intercalation-assisted Co-doped MoS 2 nanoflowers. These nanoflowers exhibit an overpotential of only 67 mV at a current density of 10 mA cm –2, which exceeds that of pristine MoS 2 (143 mV). We demonstrated that the intercalation of K enlarges the interlayer spacing of MoS 2 nanosheets and facilitates the doping of Co. The incorporation of Co effectively improves the surface charge transfer efficiency of MoS 2 and accelerates water splitting with an energy barrier of 0.12 eV. This work offers an approach to activate the inert MoS 2 basal plane by chemical intercalation and atomic doping coengineering. It can be extended to develop other functional materials beyond water splitting.