A recyclable rhodium catalyst anchored onto a bipyridine covalent triazine framework for transfer hydrogenation of N-heteroarenes in water
Jonas Everaert, Karen Leus, Hannes Rijckaert, Maarten Debruyne, Kristof Van Hecke, Rino Morent, Nathalie De Geyter, Véronique Van Speybroeck, Pascal Van Der Voort, Christian V. Stevens
Abstract
Bipyridine covalent triazine framework (bpyCTF) was used as a support material for the development of a highly efficient Rh catalyst. The heterogeneous catalyst was applied for both batch and flow transfer hydrogenation of various N-heteroarenes.
Topics & Concepts
RhodiumCatalysisTriazineCovalent bondBipyridineChemistryTransfer hydrogenation1,3,5-Triazine2,2'-BipyridineOrganic chemistryPolymer chemistryCombinatorial chemistryRutheniumCrystal structureCovalent Organic Framework ApplicationsAsymmetric Hydrogenation and CatalysisNanomaterials for catalytic reactions