Modular access to substituted germoles by intramolecular germylzincation
Seydou Kassamba, Alejandro Pérez‐Luna, Franck Ferreira, Muriel Durandetti
Abstract
Intramolecular alkyne germylzincation giving access to a wide range of germoles is achieved from triarylhydrogermanes in the presence of diethylzinc and AIBN as radical initiator.
Topics & Concepts
Intramolecular forceChemistryAlkyneDiethylzincStereochemistryCombinatorial chemistryCatalysisOrganic chemistryEnantioselective synthesisCatalytic C–H Functionalization MethodsRadical Photochemical ReactionsCatalytic Cross-Coupling Reactions