A highly polarizable concentrated dipole glass for ultrahigh energy storage
Jian Fu, Aiwen Xie, Ruzhong Zuo, Yiqian Liu, He Qi, Zongqian Wang, Quan Feng, Jinming Guo, Kun Zeng, Xuefeng Chen, Zhengqian Fu, Yifan Zhang, Xuewen Jiang, Tianyu Li, Shujun Zhang, Yuanhua Lin, Ce‐Wen Nan
Abstract
Relaxor ferroelectrics are highly desired for pulse-power dielectric capacitors, however it has become a bottleneck that substantial enhancements of energy density generally sacrifice energy efficiency under superhigh fields. Here, we demonstrate a novel concept of highly polarizable concentrated dipole glass in delicately-designed high-entropy (Bi1/3Ba1/3Na1/3)(Fe2/9Ti5/9Nb2/9)O3 ceramic achieved via substitution of multiple heterovalent ferroelectric-active principal cation species on equivalent lattice sites. The atomic-scaled polar heterogeneity of dipoles with different polar vectors between adjacent unit cells enables diffuse reorientation process but disables appreciable growth with electric fields. These unique features cause superior recoverable energy density of ~15.9 J cm−3 and efficiency of ~93.3% in bulk ceramics. We also extend the highly polarizable concentrated dipole glass to the prototype multilayer ceramic capacitor, which exhibits record-breaking recoverable energy density of ~26.3 J cm−3 and efficiency of ~92.4% with excellent temperature and cycle stability. This research presents a distinctive approach for designing high-performance energy-storage dielectric capacitors. The authors introduce the concept of highly polarizable concentrated dipole glass, involving the reduction of polar order scale from the nanoscaled polar nanodomains in traditional relaxor ferroelectrics to atomic-scale individual dipoles.