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Stable room temperature ferroelectricity in hydrogen-bonded supramolecular assemblies of ambipolar π-systems

Anurag Mukherjee, Shubhankar Barman, Anupam Ghosh, Saptarshi Chakraborty, Ayan Datta, Anuja Datta, Suhrit Ghosh

2021Chemical Science24 citationsDOIOpen Access PDF

Abstract

A molecules and reveal a significant increase in the macro-dipole moment (in the range of 10-12 Debye) going from the monomer to the oligomer(s), which provides the rationale for the origin of ferroelectricity in these supramolecular polymers.

Topics & Concepts

Ambipolar diffusionFerroelectricityMaterials scienceSupramolecular chemistryCrystallographyChemistryChemical physicsOptoelectronicsElectronCrystal structurePhysicsQuantum mechanicsDielectricConducting polymers and applicationsSupramolecular Self-Assembly in MaterialsSynthesis and Properties of Aromatic Compounds
Stable room temperature ferroelectricity in hydrogen-bonded supramolecular assemblies of ambipolar π-systems | Litcius