Illuminating milling mechanochemistry by tandem real-time fluorescence emission and Raman spectroscopy monitoring
Patrick Julien, Mihails Arhangelskis, Luzia S. Germann, Martin Etter, Robert E. Dinnebier, Andrew J. Morris, Tomislav Friščić
Abstract
We demonstrate a tandem spectroscopic method for in situ monitoring of mechanochemical reactions by fluorescence emission and Raman spectroscopy, accompanied by periodic time-dependent density-functional theory (TD-DFT) modelling.
Topics & Concepts
MechanochemistryRaman spectroscopyTandemFluorescenceDensity functional theorySpectroscopyIn situAnalytical Chemistry (journal)Materials scienceFluorescence spectroscopyChemistryPhotochemistryNanotechnologyComputational chemistryOpticsEnvironmental chemistryOrganic chemistryPhysicsQuantum mechanicsComposite materialCrystallography and molecular interactionsSpectroscopy and Quantum Chemical StudiesMolecular spectroscopy and chirality