Photoredox streamlines electrocatalysis: photoelectrosynthesis of polycyclic pyrimidin-4-ones through carbocyclization of unactivated alkenes with malonates
Minglin Tao, Feng Qin, Kaixing Gong, Xuege Yang, Lou Shi, Qiaowen Chang, Deqiang Liang
Abstract
A new photoelectrocatalytic mode permits the synthesis of polycyclic pyrimidin-4-ones through dehydrogenative cyclization of malonates with unactivated alkenes.
Topics & Concepts
ChemistryElectrocatalystStreamlines, streaklines, and pathlinesCombinatorial chemistryPhysicsElectrodeElectrochemistryThermodynamicsPhysical chemistryRadical Photochemical ReactionsSulfur-Based Synthesis TechniquesCatalytic C–H Functionalization Methods