An octahedral cobalt(<scp>iii</scp>) complex based on cheap 1,2-phenylenediamine as a bifunctional metal-templated hydrogen bond donor catalyst for fixation of CO<sub>2</sub> with epoxides under ambient conditions
Mikhail A. Emelyanov, Nadezhda V. Stoletova, Alexey A. Lisov, Michael G. Medvedev, Alexander F. Smol’yakov, Victor I. Maleev, Vladimir A. Larionov
Abstract
An octahedral cobalt(<sc>iii</sc>) complex based on cheap 1,2-phenylenediamine operates as an efficient bifunctional hydrogen bond donor catalyst in cycloaddition of epoxides with CO<sub>2</sub> under ambient conditions and solvent- and co-catalyst-free conditions.
Topics & Concepts
BifunctionalCobaltCatalysisOctahedronChemistryHydrogen bondCycloadditionBifunctional catalystMetalPolymer chemistryInorganic chemistryOrganic chemistryMoleculeCrystal structureCarbon dioxide utilization in catalysisCO2 Reduction Techniques and CatalystsChemical Synthesis and Reactions