Calcium-Looping Performance of Biomineralized CaCO<sub>3</sub> for CO<sub>2</sub> Capture and Thermochemical Energy Storage
Juan Arcenegui-Troya, Pedro E. Sánchez‐Jiménez, Antonio Perejón, José Manuel Valverde, Ricardo Chacartegui, Luis A. Pérez‐Maqueda
Abstract
The commercial deployment of calcium-looping (CaL)-based technologies relies on the availability of nontoxic, widely available and cheap CaCO3 rich materials. Biomineralized CaCO3 from waste amply fulfills the aforementioned requirements. In the present work, we study the performance of eggshell and snail shell from food waste as CaO precursors for CaL applications. The results obtained suggest the feasible use of these waste materials. The multicyclic conversion exhibited by biomineralized CaCO3 was comparable to that demonstrated by limestone, which is a commonly proposed material for CaL applications. In addition, the temperature needed to completely calcine biomineralized CaCO3 in short residence times is lower than that required to fully calcine limestone. This would mitigate the energy cost of the technology.