Research Progress of Rare Earth Metal–Organic Frameworks on Pollutant Monitoring
Qingbo Yu, Meng Wang, Xiujuan Feng, Xianhua Li
Abstract
Rare earth metal–organic frameworks (RE-MOFs) are mainly composed of rare earth ions and organic ligands, taking advantage of the strengths of both metal–organic frameworks (MOFs) and rare earth ions. Rare earth ions have the unique feature of unfilled 4f electron shells, which endows them with higher coordination numbers, unique luminescence properties, larger Stokes shifts, longer fluorescence lifetimes, and higher luminescence quantum efficiency. The MOFs combined with a variety of organic ligands can effectively guide the antenna effect to sensitize the rare earth ions and thus enhance the photon emission, making RE-MOFs a promising material in the field of fluorescent probes. In this paper, the recent advances in design principles, strategies, synthesis means, and monitoring mechanisms of RE-MOF materials for pollutant monitoring are presented. The intrinsic correlation between the luminescence performance of RE-MOFs, the detection of contaminants and the selection of organic ligands, and the adjustment of the MOF backbone structure is systematically and comprehensively discussed. Finally, the future development direction and application prospects of RE-MOF materials are summarized and discussed.