Asymmetric Total Syntheses of (+)-Davisinol and (+)-18-Benzoyldavisinol: A HAT-Initiated Transannular Redox Radical Approach
Kuan Yu, Fengjie Yao, Qingrui Zeng, Hujun Xie, Hanfeng Ding
Abstract
-diterpenoid alkaloids and pave the way for their modular syntheses.
Topics & Concepts
ChemistryCycloadditionRedoxKinetic resolutionRadical cyclizationTerpenoidTotal synthesisStereochemistryCombinatorial chemistryModular designOrganic chemistryEnantioselective synthesisCatalysisOperating systemComputer sciencePlant-based Medicinal ResearchBioactive Natural Diterpenoids ResearchAlkaloids: synthesis and pharmacology