Iron-catalyzed ring-opening of cyclic carboxylic acids enabled by photoinduced ligand-to-metal charge transfer
Jia‐Lin Tu, Han Gao, Mengqi Luo, Lulu Zhao, Chao Yang, Lin Guo, Wujiong Xia
Abstract
A decarboxylative ring-opening reaction of cyclic tertiary carboxylic acids via an iron-catalyzed photoinduced ligand-to-metal charge transfer (LMCT) process is herein reported.
Topics & Concepts
Ring (chemistry)CatalysisChemistryLigand (biochemistry)MetalCharge (physics)PhotochemistryCarboxylic acidPolymer chemistryOrganic chemistryReceptorBiochemistryPhysicsQuantum mechanicsCatalytic C–H Functionalization MethodsRadical Photochemical ReactionsSulfur-Based Synthesis Techniques