Switching on thermal and light-induced spin crossover by desolvation of [Fe(3-bpp)<sub>2</sub>](XO<sub>4</sub>)<sub>2</sub>·solvent (X = Cl, Re) compounds
Abdelhak Djemel, Olaf Stefańczyk, Cédric Desplanches, Kunal Kumar, Rachid Delimi, Farouk Benaceur, Shin‐ichi Ohkoshi, Guillaume Chastanet
Abstract
Two new complexes [Fe(3-bpp)<sub>2</sub>](XO<sub>4</sub>)<sub>2</sub>·solv (X = Cl, <bold>1</bold> and Re, <bold>2</bold>) have been prepared. Both systems show desolvation-assisted spin crossover (DASCO) and light-induced excited spin-state trapping (LIESST) phenomena.
Topics & Concepts
Spin crossoverExcited stateSpin statesSolventChemistryThermalSpin (aerodynamics)TrappingMaterials scienceCrystallographyPhysical chemistryAtomic physicsPhysicsInorganic chemistryThermodynamicsEcologyBiologyOrganic chemistryMagnetism in coordination complexesMetal-Catalyzed Oxygenation MechanismsLanthanide and Transition Metal Complexes