Experimental and Numerical Simulation of Molybdenum Oxide Films with Wide Bandgap and High Work Function for Carrier-Selective Contact Solar Cells
Muhammad Quddamah Khokhar, Kumar Mallem, Xinyi Fan, Youngkuk Kim, Shahzada Qamar Hussain, Eun‐Chel Cho, Junsin Yi
Abstract
In silicon heterojunction (SHJ) solar cells, a wide bandgap material with a high work function is widely used as the hole extraction pathway to attain high efficiency. We introduced a molybdenum oxide (MoO x ) film as an effective hole-transfer layer in carrier selective contact (CSC) solar cells by virtue of its wide bandgap along with high work function. The passivation characteristics, optical and electrical properties of MoO x films were investigated by differing thickness and work function. The combination of 6 nm hydrogenated intrinsic amorphous silicon (a-Si:H(i)) and 7 nm thermally evaporated MoO x passivation layers provides excellent passivation properties, reduces carrier recombination, and improves the cell performance. The synthesized CSC solar cells showed promising results, with an open-circuit voltage (V oc ) of 708 mV, short-circuit current (J sc ) = 37.38 mA cm −2 , fill factor (FF) = 74.59%, and efficiency ( η ) = 19.75%. To justify the obtained result, an AFORS HET simulation was conducted based on the experimental results. The high work function and wide bandgap MoO x /c-Si(n) interface developed a considerable built-in potential and suppressed the electron–hole pair recombination mechanism. The CSC solar cell’s simulated performance was enhanced from 1.62 to 23.32% by varying the MoO x work function (Φ MoOx ) from 4.5 to 5.7 eV.