<i>In situ</i> Raman and FTIR spectroscopic study on the formation of the isomers MIL-68(Al) and MIL-53(Al)
Heidemarie Embrechts, Martin Kriesten, Matthias Ermer, Wolfgang Peukert, Martin Hartmann, Monica Distaso
Abstract
BDC in solution is proposed to hinder MIL-68(Al) formation by serving as a molecular template for the rhombic MIL-53(Al) pore channels.
Topics & Concepts
Terephthalic acidFormic acidChemistryMetal-organic frameworkRaman spectroscopyFourier transform infrared spectroscopyLinkerHydrogen bondInorganic chemistryCrystallographyChemical engineeringMoleculeOrganic chemistryPhysicsOperating systemAdsorptionEngineeringPolyesterComputer scienceOpticsMetal-Organic Frameworks: Synthesis and ApplicationsX-ray Diffraction in CrystallographyNanoplatforms for cancer theranostics