Reducing the internal reorganization energy <i>via</i> symmetry controlled π-electron delocalization
Chi-Chi Wu, Elise Y. Li, Pi‐Tai Chou
Abstract
state reduces the reorganization energy. The principles proposed in this study are also translated into various pathways of canonically equivalent π-conjugation resonances to represent intramolecular π-delocalization, the concept of which may be applicable, in a facile manner, to improve the emission efficiency especially in the NIR region.
Topics & Concepts
Delocalized electronSymmetry (geometry)Electron delocalizationElectronPhysicsChemical physicsMolecular physicsAtomic physicsCondensed matter physicsQuantum mechanicsMathematicsGeometryAdvanced Chemical Physics StudiesMolecular Junctions and NanostructuresSynthesis and Properties of Aromatic Compounds