From spin-crossover to single molecule magnetism: tuning magnetic properties of Co(<scp>ii</scp>) bis-ferrocenylterpy cations via supramolecular interactions with organocyanide radical anions

Haomiao Xie, Kuduva R. Vignesh, Xuan Zhang, Kim R. Dunbar

2020Journal of Materials Chemistry C16 citationsDOI Open Access PDF

Abstract

TCNQ (7,7,8,8-tetracyanoquinodimethane) anion-radical derivatives were used to fine tune the magnetic properties of the [CoII(Fctp)2]2+ (Fctp = 4′-(2-ferrocenyl)-2,2′:6′2′′-terpyridine) cation in the solid state.

Topics & Concepts

MagnetismSupramolecular chemistryIonSpin crossoverTerpyridineCrystallographyMaterials scienceTetracyanoquinodimethaneMoleculeSpin statesInorganic chemistryChemistryCondensed matter physicsCrystal structureMetalOrganic chemistryPhysicsMetallurgyMagnetism in coordination complexesOrganic and Molecular Conductors ResearchOrganic Light-Emitting Diodes Research

From spin-crossover to single molecule magnetism: tuning magnetic properties of Co(<scp>ii</scp>) bis-ferrocenylterpy cations <i>via</i> supramolecular interactions with organocyanide radical anions

Abstract

Topics & Concepts