Litcius/Paper detail

Recent Advances in the High‐Valent Cobalt‐Catalyzed C−H Functionalization of <i>N</i>‐Heterocycles

Devesh Chandra, XXXXXXX Manisha, Upendra Sharma

2021The Chemical Record27 citationsDOI

Abstract

Direct functionalization of heterocycles using C-H activation widely relies on the precious metal complexes. In past decade, the use of earth abundant and inexpensive transition metal to functionalize heterocycles has become an attractive alternate strategy. This concept is also interesting due to the unique reactivity pattern of these inexpensive metals. In this context we and other research groups have utilized the high-valent cobalt complexes as an inexpensive and readily available catalyst for the functionalization of heterocycles. In this review, we intend to brief recent progress made in the area of high-valent cobalt complexes catalyzed C-H functionalization of N-containing heterocycles.

Topics & Concepts

Surface modificationCobaltCatalysisContext (archaeology)Reactivity (psychology)Transition metalCombinatorial chemistryChemistryNanotechnologyMaterials scienceOrganic chemistryPaleontologyPhysical chemistryMedicinePathologyBiologyAlternative medicineCatalytic C–H Functionalization MethodsSynthesis and Catalytic ReactionsAsymmetric Hydrogenation and Catalysis