Synthesis of a New Class of Macrocyclic Phosphorus-Containing Tri- and Diperoxides in the Presence of Lanthanide Catalysts
Nataliya N. Makhmudiyarova, I. R. Ishmukhametova, А. Г. Ибрагимов, U. M. Dhzemilev
Abstract
A promising method for the synthesis of a new class of macrocyclic phosphorus-containing tri- and diperoxides was developed. The method is based on catalytic ring transformation reactions of heptaoxadispiroalkanes, pentaoxacanes, and pentaoxadispiroalkanes with phenylphosphine followed by oxidation of the reaction mixture with H2O2.
Topics & Concepts
ChemistryPhenylphosphineCatalysisLanthanidePhosphorusRing (chemistry)Combinatorial chemistryTransformation (genetics)Organic chemistryPhosphineBiochemistryIonGeneOrganic Chemistry Cycloaddition ReactionsPhosphorus compounds and reactionsOrganophosphorus compounds synthesis