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Cobalt-catalyzed highly selective hydroxylation of organohydrosilanes and hydrosiloxanes

Peng Guo, Ling‐Chao Cheng, Xinglei He, Ke‐Yin Ye

2022Organic Chemistry Frontiers14 citationsDOI

Abstract

The highly selective and scalable dehydrogenative hydroxylation of hydrosilanes, featuring a low loading of the Earth-abundant cobalt catalyst, water as the green oxidant, and good generality for various hydrosilanes, is reported.

Topics & Concepts

HydroxylationChemistryCobaltCatalysisCombinatorial chemistryOrganic chemistryEnzymeOrganoboron and organosilicon chemistryCatalytic Cross-Coupling ReactionsChemical Synthesis and Reactions
Cobalt-catalyzed highly selective hydroxylation of organohydrosilanes and hydrosiloxanes | Litcius