Selective electrocatalytic hydroboration of aryl alkenes
Yahui Zhang, Xiangyu Zhao, Ce Bi, Wenqi Lu, Mengyuan Song, Dongdong Wang, Guangyan Qing
Abstract
A CH<sub>3</sub>CN-involved electrochemical mono- or di-functional borylation reaction with alkenes and HBpin as substrates was reported. Functional group transformation and gram-scale synthesis demonstrated the utility of this method and showed great potential application.
Topics & Concepts
HydroborationBorylationChemistryArylFunctional groupElectrochemistryAlkeneCombinatorial chemistryTransformation (genetics)Organic chemistryCatalysisGeneAlkylElectrodeBiochemistryPhysical chemistryPolymerRadical Photochemical ReactionsCatalytic C–H Functionalization MethodsOrganoboron and organosilicon chemistry