Low-Temperature Selective Catalytic Reduction of NO with NH<sub>3</sub> over a Biochar-Supported Perovskite Oxide Catalyst
Xiaoxiong Fan, Lifang Hao, Xiangyu Gu, Songgeng Li
Abstract
Maintaining high denitration efficiency for the selective catalytic reduction with ammonia (NH 3 -SCR) at low temperatures is challenging. In this work, a modified biochar-supported perovskite oxide catalyst was synthesized and implemented to NO conversion in the low-temperature range of 100–250 °C. Different modification methods were compared, where the combination of nitric acid and air oxidation treatment endowed biochar with abundant acidic surface oxygen-containing groups and a higher specific surface area as a support. The perovskite oxide (LaMnO 3 ) and the LaMnO 3 /biochar catalysts were prepared to investigate the interactions between the catalyst and the support. The LaMnO 3 /biochar catalyst exhibited excellent denitration efficiency and good N 2 selectivity, achieving over 80% NO conversion within the entire temperature range of 100–250 °C ( S N 2 > 90%), and the highest NO conversion reached 95.8% at 225 °C ( S N 2 = 95.4%). This catalyst provided synergistic adsorption capacity for NH 3 as a result of the acidic function of perovskite oxide and acidic oxygen-containing functional groups of the modified biochar support. Additionally, LaMnO 3 showed an eminent redox capability for NO conversion due to the high content of Mn 4+ and chemically adsorbed oxygen species. Finally, NH 3 -SCR reaction mechanisms were proposed on the basis of transient response experiments and in situ diffuse reflectance infrared Fourier transform spectra (DRIFTS) characterization.