Impact of Pore Structure on Two‐Electron Oxygen Reduction Reaction in Nitrogen‐Doped Carbon Materials: Rotating Ring‐Disk Electrode vs. Flow Cell
Hui Xu, Xue‐Hui Lv, Haoyu Wang, Jin‐Yu Ye, Jiayin Yuan, Yucheng Wang, Zhi‐You Zhou, Shi‐Gang Sun
Abstract
Abstract The impact of pore structure on the two‐electron oxygen reduction reaction (ORR) in nitrogen‐doped carbon materials is currently under debate, and previous studies are mainly limited to the rotating ring‐disk electrode (RRDE) rather than the practical flow cell (FC) system. In this study, assisted by a group of reliable pore models, the impact of two pore structure parameters, that is, Brunauer–Emmett–Teller surface area ( S BET ) and micropore surface fraction ( f micro ), on ORR activity and selectivity are investigated in both RRDE and FC. The ORR mass activity correlates positively to the S BET in the RRDE and FC because a higher S BET can host more active sites. The H 2 O 2 selectivity is independent of f micro in the RRDE but correlates negatively to f micro in the FC. The inconsistency results from different states of the electrode in the RRDE and the FC. These insights will guide the design of carbon materials for H 2 O 2 synthesis.