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Effect of icosahedral phase formation on the stress corrosion cracking (SCC) behaviors of the as-cast Mg-8%Li (in wt.%) based alloys

Shuo Wang, Daokui Xu, Dongliang Wang, Zhiqiang Zhang, Baojie Wang

2022Journal of Magnesium and Alloys23 citationsDOIOpen Access PDF

Abstract

Through exploring the stress corrosion cracking (SCC) behaviors of the as-cast Mg-8%Li and Mg-8%Li-6%Zn-1.2%Y alloys in a 0.1 M NaCl solution, it revealed that the SCC susceptibility index (ISCC) of the Mg-8%Li alloy was 47%, whilst the ISCC of the Mg-8%Li-6%Zn-1.2%Y alloy was 68%. Surface, cross-sectional and fractography observations indicated that for the Mg-8%Li alloy, the α-Mg/β-Li interfaces acted as the preferential crack initiation sites and propagation paths during the SCC process. With regard to the Mg-8%Li-6%Zn-1.2%Y alloy, the crack initiation sites included the I-phase and the interfaces of I-phase/β-Li and α-Mg/β-Li, and the preferential propagation paths were the I-phase/β-Li and α-Mg/β-Li interfaces. Moreover, the SCC of the two alloys was concerned with hydrogen embrittlement (HE) mechanism.

Topics & Concepts

Materials scienceAlloyStress corrosion crackingFractographyMetallurgyPhase (matter)Hydrogen embrittlementCorrosionEmbrittlementCrackingComposite materialMicrostructureChemistryOrganic chemistryMagnesium Alloys: Properties and ApplicationsHydrogen Storage and MaterialsCorrosion Behavior and Inhibition
Effect of icosahedral phase formation on the stress corrosion cracking (SCC) behaviors of the as-cast Mg-8%Li (in wt.%) based alloys | Litcius