Ni-Based Catalyst for Carbon Dioxide Methanation: A Review on Performance and Progress
Nur Diyan Mohd Ridzuan, Maizatul Shima Shaharun, Mohd Azrizan Bin Anawar, Israf Ud Din
Abstract
Catalytic conversion of CO2 into methane is an attractive method because it can alleviate global warming and provide a solution for the energy depletion crisis. Nickel-based catalysts were commonly employed in such conversions due to their high performance over cost ratio. However, the major challenges are that Ni tends to agglomerate and cause carbon deposition during the high-temperature reaction. In the past decades, extensive works have been carried out to design and synthesize more active nickel-based catalysts to achieve high CO2 conversion and CH4 selectivity. This review critically discusses the recent application of Ni-based catalyst for CO2 methanation, including the progress on the effect of supporting material, promoters, and catalyst composition. The thermodynamics, kinetics, and mechanism of CO2 methanation are also briefly addressed.