A Comparative Study on Oxidation of Acidic Red 18 by Persulfate with Ferrous and Ferric Ions
Xin Li, Lijing Yuan, Liangfu Zhao
Abstract
Ferrous and ferric salts were tested for the persulfate activation (PS/Fe2+ and PS/Fe3+) and the oxidation of Acid Red 18 (AR18). A complete removal was attained after 90 min in both PS/Fe2+ and PS/Fe3+ processes with the persulfate concentration of 6 mM. High concentrations of PS, Fe2+, and Fe3+ promoted the AR18 degradation in both processes and the optimized pH were 3 and 3.3 for PS/Fe2+ and PS/Fe3+ processes, respectively. The mechanism of PS activation by Fe3+ was also investigated. It was found that hydroxyl radical (HO•) and sulfate radical (SO4−•) were formed and acted as dominating radicals in both processes. It is also deduced that Fe recycle offers Fe2+ for PS activation in PS/Fe3+ process to produce HO• and SO4−•. The less radical side reactions lead to a higher contribution of HO• and SO4−• on AR18 degradation in PS/Fe3+ process.