Rational Selection of the Lewis Base Molecules Targeted for Lead-Based Defects of Perovskite Solar Cells: The Synergetic Co-passivation of Carbonyl and Carboxyl Groups
Pengfei Wang, Jing Liu, Wenzhe Shang, Ting Xu, Minhuan Wang, Yantao Shi, Rui Cai, Jiming Bian
Abstract
Defect passivation through Lewis acid–base chemistry has recently attracted significant interest because of its proven ability to improve the power conversion efficiency (PCE) and stability of perovskite solar cells (PSCs). However, tedious trial-and-error procedures are commonly used for the selection of Lewis molecules due to their abundant variety. Herein, two typical Lewis base molecules, the M molecule containing only carbonyl groups and the 3M molecule containing both carbonyl and carboxyl groups, are proposed to passivate the Pb-based defects and mitigate their negative impacts on PSC performance. The results indicated that much stronger coordination bonds can be formed between the 3M molecule and uncoordinated Pb 2+ than with the M molecule. Because of the benefit from the synergetic co-passivation effect of carbonyl and carboxyl groups, an impressive maximum PCE of 24.07% was achieved via 3M modification. More importantly, the modified devices demonstrated remarkably improved operational stability.