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Chemical Recycling of Plastic Waste via Production of Ethylene from Gasification Syngas

Matthias Maier, Corinna Netzer, Thomas A. Adams

2024Industrial & Engineering Chemistry Research16 citationsDOIOpen Access PDF

Abstract

High Resolution Image Download MS PowerPoint Slide We investigated the plastic waste to ethylene (PtE) process through steam-oxygen gasification, methanation, and oxidative coupling of methane. Gasification was modeled using a stochastic reactor model, while the downstream process was modeled using Aspen Plus. The carbon efficiency of the process ranges from 13 to 23%, depending on feedstock used. We investigated a base case scenario with CO 2 venting and a case with CO 2 compression and transport. While 5.7 kgCO 2eq /kg ethylene can be avoided in the former one, the latter one leads to an avoidance of 18.4 kgCO 2eq /kg ethylene. The costs of CO 2 avoided are 666 €/tCO 2eq and 230 €/tCO 2eq, respectively.

Topics & Concepts

SyngasWaste managementProduction (economics)EthyleneEnvironmental sciencePulp and paper industryChemistryProcess engineeringOrganic chemistryCatalysisEngineeringMacroeconomicsEconomicsZeolite Catalysis and SynthesisThermochemical Biomass Conversion ProcessesCatalysts for Methane Reforming
Chemical Recycling of Plastic Waste via Production of Ethylene from Gasification Syngas | Litcius