Placing gold on a π<sup>+</sup>-surface: ligand design and impact on reactivity
Wei‐Chun Liu, François P. Gabbaı̈
Abstract
-butylamide, and 2-allyl-2-(2-propynyl)malonate. Comparison with the significantly less active acridinium and the 9-oxa-10-boraanthracene analogues reinforces this conclusion.
Topics & Concepts
Ligand (biochemistry)Reactivity (psychology)ChemistryMoietyPhosphineMalonateMedicinal chemistryChlorideDecompositionPhenylboronic acidCatalysisStereochemistryOrganic chemistryMedicinePathologyBiochemistryReceptorAlternative medicineCatalytic Alkyne ReactionsAsymmetric Hydrogenation and CatalysisOrganometallic Complex Synthesis and Catalysis