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Many-Body Dispersion

Peng Xu, Melisa Alkan, Mark S. Gordon

2020Chemical Reviews31 citationsDOI

Abstract

A broad range of approaches to many-body dispersion are discussed, including empirical approaches with multiple fitted parameters, augmented density functional-based approaches, symmetry adapted perturbation theory, and a supermolecule approach based on coupled cluster theory. Differing definitions of "body" are considered, specifically atom-based vs molecule-based approaches.

Topics & Concepts

ChemistrySupermoleculeDensity functional theoryDispersion (optics)Perturbation theory (quantum mechanics)Range (aeronautics)Statistical physicsComputational chemistryMoleculeChemical physicsQuantum mechanicsPhysicsAerospace engineeringEngineeringOrganic chemistryAdvanced Chemical Physics StudiesSpectroscopy and Quantum Chemical StudiesCold Atom Physics and Bose-Einstein Condensates
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